Chemical Principles 8th Edition by Steven S. Zumdahl – Test Bank

 

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Sample Test

Chapter_03_Stoichiometry

 

 

1. Bromine exists naturally as a mixture of bromine-79 and bromine-81 isotopes. An atom of bromine-79 contains

 

a.

79 protons, 79 electrons, and 35 neutrons.

 

b.

35 protons, 44 neutrons, and 35 electrons.

 

c.

44 protons, 44 electrons, and 35 neutrons.

 

d.

34 protons and 35 electrons only.

 

e.

35 protons, 79 neutrons, and 35 electrons.

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.1

KEYWORDS:  

atomic theory of matter | early atomic theory | general chemistry | isotope

 

2. The atomic mass of rhenium is 186.2. Given that 37.1% of natural rhenium is rhenium-185, what is the other stable isotope?

 

a.

 

b.

 

c.

 

d.

 

e.

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.1

KEYWORDS:  

atomic theory of matter | early atomic theory | general chemistry | isotope

 

3. Consider the new element moonium, atomic number 118, atomic mass 273.2 g. The nucleus of an atom of moonium-273 contains

 

a.

118 protons, 118 alpha particles.

 

b.

118 protons, 155 neutrons.

 

c.

118 protons, 273neutrons.

 

d.

118protons, 155 neutrons, 118 electrons.

 

e.

118protons, 118neutrons.

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.1

KEYWORDS:  

atomic theory of matter | early atomic theory | general chemistry | nuclear structure

 

4. For a new element, 60.54% is an isotope with mass 282.1 amu, 3.28% is an isotope with mass 283.2 amu, and 36.18% is an isotope with mass 284.6 amu.  Calculate the average atomic mass of this new element.

 

a.

283.3 amu

 

b.

849.9 amu

 

c.

282.1 amu

 

d.

283.0 amu

 

e.

314.5 amu

 

ANSWER:  

d

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.1

KEYWORDS:  

atomic theory of matter | atomic weight | early atomic theory | general chemistry | relative atomic mass

 

5. The average mass of a boron atom is 10.81.  If you were able to isolate a single boron atom, what is the chance that you would randomly get an atom with mass 10.81?

 

a.

greater than 50%

 

b.

0%

 

c.

0.81%

 

d.

10.81%

 

e.

about 11%

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.1

KEYWORDS:  

atomic theory of matter | atomic weight | early atomic theory | general chemistry | relative atomic mass

 

6. Indium has atomic number 49 and atomic mass 114.8 g.  Naturally occurring indium contains a mixture of indium-112 and indium-115 in an atomic ratio of approximately

 

a.

75/25.

 

b.

25/75.

 

c.

6/94.

 

d.

50/50.

 

e.

94/6.

 

ANSWER:  

c

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.1

KEYWORDS:  

atomic theory of matter | early atomic theory | general chemistry | isotope

 

7. Boron naturally occurs in two isotopic forms.  The more common isotope is 11B (atomic mass 11.01 amu), which is 80.00% abundant.  The average atomic mass of boron is 10.81.  What is the mass of the other isotope?

 

a.

10.91 amu.

 

b.

10.01 amu.

 

c.

10.81 amu.

 

d.

11.00 amu.

 

e.

11.01 amu.

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.1

KEYWORDS:  

atomic theory of matter | atomic weight | early atomic theory | general chemistry | relative atomic mass

 

8. A sample of iron weighing 15.0 g contains how many moles of iron atoms?

 

a.

3.72 mol

 

b.

0.269 mol

 

c.

0.118 mol

 

d.

0.577 mol

 

e.

0.0780 mol

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.2

KEYWORDS:  

general chemistry | mass and moles of substance | mole | mole calculations | stoichiometry

 

9. A single atom of an element weighs 5.81 × 10–23 g.  Identify the isotope.

 

a.

35Cl

 

b.

103Rh

 

c.

80Br

 

d.

45Sc

 

e.

none of these

 

ANSWER:  

a

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.2

KEYWORDS:  

general chemistry | mass and moles of substance | mole | mole calculations | stoichiometry

 

10. Iron is biologically important in the transport of oxygen by red blood cells from the lungs to the various organs of the body. In the blood of an adult human, there are approximately 2.60 × 1013 red blood cells with a total of 2.90 g of iron. On the average, how many iron atoms are present in each red blood cell? (molar mass for Fe = 55.85 g)

 

a.

8.33 × 10–10

 

b.

1.20 × 109

 

c.

5.19 × 10–2

 

d.

3.12 × 1022

 

e.

2.60 × 1013

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.2

KEYWORDS:  

general chemistry | mass and moles of substance | mole | mole calculations | stoichiometry

 

11. An alkali metal oxide contains 83.01% metal by mass.  Determine the identity of the metal.

 

a.

Cs

 

b.

Li

 

c.

K

 

d.

Na

 

e.

Rb

 

ANSWER:  

c

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.2
3.3

KEYWORDS:  

determining chemical formulas | general chemistry | mass percentage | stoichiometry

 

12. What is the molar mass of ethanol (C2H5OH)?

 

a.

46.07

 

b.

62.07

 

c.

45.07

 

d.

38.90

 

e.

34.17

 

ANSWER:  

a

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.3

KEYWORDS:  

general chemistry | mass and moles of substance | molecular weight | stoichiometry

 

13. For which of the following compounds does 1.0 g represent 2.27 × 10–2 mol?

 

a.

​H2O

 

b.

​C2H6

 

c.

NH3

 

d.

​CO2

 

e.

​CO

 

ANSWER:  

d

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.3

KEYWORDS:  

general chemistry | mass and moles of substance | molecular weight | stoichiometry

 

14. Which compound has the smallest molar mass?

 

a.

C2H6

 

b.

CH3Cl

 

c.

CO2

 

d.

C2H4O

 

e.

none of these

 

ANSWER:  

a

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.3

KEYWORDS:  

general chemistry | mass and moles of substance | molecular weight | stoichiometry

 

15. For which compound does 0.256 mole weigh 12.9 g?

 

a.

C2H4O2

 

b.

C2H6

 

c.

CH3Cl

 

d.

CO2

 

e.

C2H4O

 

ANSWER:  

c

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.3

KEYWORDS:  

general chemistry | mass and moles of substance | molecular weight | stoichiometry

 

16. Calculate the molar mass of a sample if a single molecule weighs 5.34 × 10–23 g.

 

a.

12.0 g/mol

 

b.

5.34 × 10–23 g/mol

 

c.

1.13 × 1046 g/mol

 

d.

32.2 g/mol

 

e.

none of these

 

ANSWER:  

d

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.3

KEYWORDS:  

general chemistry | mass and moles of substance | molecular weight | stoichiometry

 

17. How many moles of Pmolecules molecules are in 145.2 g of  phosphorus?

 

a.

1.172 mol

 

b.

1.452 × 101 mol

 

c.

4.688 mol

 

d.

2.411 × 101 mol

 

e.

1.799 × 104 mol

 

ANSWER:  

a

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.3

KEYWORDS:  

general chemistry | mass and moles of substance | mole | mole calculations | stoichiometry

 

18. What is the mass (in grams) of one molecule of phosphorus pentachloride?

 

a.

1.25 × 1026 g

 

b.

3.46 × 10–22 g

 

c.

1.10 × 10–22 g

 

d.

208.22 g

 

e.

1.00 g

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.3

KEYWORDS:  

general chemistry | mass and moles of substance | mole | mole calculations | stoichiometry

 

19. How many molecules of ammonia are present in 6.9 g of ammonia?

 

a.

6.7 × 10–25

 

b.

4.1 × 101

 

c.

8.3 × 1023

 

d.

4.2 × 1024

 

e.

2.4 × 1023

 

ANSWER:  

e

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.3

KEYWORDS:  

general chemistry | mass and moles of substance | mole | mole calculations | stoichiometry

 

20. How many atoms of hydrogen are present in 4.0 g of ammonia?

 

a.

7.8 × 1024

 

b.

0.70

 

c.

4.2 × 1023

 

d.

1.2 × 10–24

 

e.

1.8 × 1024

 

ANSWER:  

c

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.3

KEYWORDS:  

general chemistry | mass and moles of substance | mole | mole calculations | stoichiometry

 

21. The mass of 0.82 mol of a diatomic molecule is 131.3 g.  Identify the molecule.

 

a.

Xe

 

b.

Cl2

 

c.

I2

 

d.

F2

 

e.

Br2

 

ANSWER:  

e

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.3

KEYWORDS:  

general chemistry | mass and moles of substance | molecular weight | stoichiometry

 

22. Roundup, an herbicide manufactured by Monsanto, has the formula C3H8NO5P. How many moles of molecules are there in a 500.-g sample of Roundup?

 

a.

84.5

 

b.

2.96

 

c.

0.338

 

d.

1.75

 

e.

none of these

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.3

KEYWORDS:  

general chemistry | mass and moles of substance | mole | mole calculations | stoichiometry

 

23. What mass of styrene (molar mass 104.1 g/mol) contains 4.50 × 1020 molecules of styrene?

 

a.

7.78 × 10–2 g

 

b.

7.48 × 104 g

 

c.

0.00778 g

 

d.

7.48 × 10–4 g

 

e.

7.48 × 10–3 g

 

ANSWER:  

a

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.3

KEYWORDS:  

general chemistry | mass and moles of substance | mole | mole calculations | stoichiometry

 

24. Phosphorus has the molecular formula P4 and sulfur has the molecular formula S8. How many grams of phosphorus contain the same number of molecules as 6.41 g of sulfur?

 

a.

6.19 g

 

b.

6.41 g

 

c.

3.21 g

 

d.

3.10 g

 

e.

none of these

 

ANSWER:  

d

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.3

KEYWORDS:  

general chemistry | mass and moles of substance | mole | mole calculations | stoichiometry

 

25. The molar mass of the insecticide dibromoethane is 187.9 g/mol.  Its molecular formula is C2H4Br2.  How many atoms of carbon are in a sample of dibromoethane weighing 1.879 g?

 

a.

none of these

 

b.

1.204 × 1022

 

c.

6.022 × 100.21

 

d.

6.022 × 1021

 

e.

12.04 × 1044

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.3

KEYWORDS:  

general chemistry | mass and moles of substance | mole | mole calculations | stoichiometry

 

26. A given sample of xenon fluoride contains molecules of a single type, XeFn, where n is some whole number. Given that 9.03 × 1020 molecules of XeFn weigh 0.311 g, calculate n.

 

a.

2

 

b.

4

 

c.

1

 

d.

none of these

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.3

KEYWORDS:  

determining chemical formulas | empirical formula | general chemistry | stoichiometry

 

27. NaHCO3 is the active ingredient in baking soda. How many grams of oxygen are in 0.36 g of NaHCO3?

 

a.

0.0043 g

 

b.

0.21 g

 

c.

0.013g

 

d.

0.069 g

 

e.

1.1 g

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.3

KEYWORDS:  

general chemistry | mass and moles of substance | mole | mole calculations | stoichiometry

 

28. The empirical formula of sugar is CH2O and its molar mass is 180.2 g/mole.  If one teaspoon of sugar weighs 3.50 g, how many moles of sugar and how many molecules of sugar are present?

 

a.

0.0194 mole, 3.24 × 1026 molecules

 

b.

0.0295 mole, 1.78 × 1022 molecules

 

c.

0.0583 mole, 3.51 × 1022 molecules

 

d.

0.0194 mole, 1.17 × 1022 molecules

 

e.

0.117 mole, 7.03 × 1022 molecules

 

ANSWER:  

d

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.3

KEYWORDS:  

general chemistry | mass and moles of substance | mole | mole calculations | stoichiometry

 

29. Compound X2Y is 60% X by mass.  Calculate the percent Y by mass of the compound X2Y2.

 

a.

30%

 

b.

80%

 

c.

40%

 

d.

20%

 

e.

60%

 

ANSWER:  

e

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.3
3.4

KEYWORDS:  

determining chemical formulas | general chemistry | mass percentage | stoichiometry

 

30. Cortisone consists of molecules, each of which contains 21 atoms of carbon (plus other atoms). The mass percentage of carbon in cortisone is 69.98%. What is the molar mass of cortisone?

 

a.

287.6 g/mol

 

b.

360.4 g/mol

 

c.

176.5 g/mol

 

d.

252.2 g/mol

 

e.

312.8 g/mol

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.3
3.5

KEYWORDS:  

general chemistry | mass and moles of substance | molecular weight | stoichiometry

 

31. An oxybromate compound, NaBrOx, where x is a whole number, is analyzed and found to contain 52.95% Br by mass.  What is x?

 

a.

0

 

b.

1

 

c.

2

 

d.

3

 

e.

4

 

ANSWER:  

d

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.3
3.5

KEYWORDS:  

determining chemical formulas | empirical formula | general chemistry | stoichiometry

 

32. Which of the following contains the greatest percentage of nitrogen by mass?

 

a.

NH3

 

b.

HCN

 

c.

C6H4N3O6

 

d.

N2O

 

e.

NO2

 

ANSWER:  

a

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.4

KEYWORDS:  

determining chemical formulas | general chemistry | mass percentage | stoichiometry

 

33. The molar mass of the insecticide dibromoethane is 187.9. Its molecular formula is C2H4Br2. What percent by mass of bromine does dibromoethane contain?

 

a.

50.0%

 

b.

37.8%

 

c.

42.5%

 

d.

89.3%

 

e.

85.0%

 

ANSWER:  

e

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.4

KEYWORDS:  

determining chemical formulas | general chemistry | mass percentage | stoichiometry

 

34. A substance contains 3.024 g hydrogen, 30.97 g phosphorus, and 64.00 g oxygen.  How many grams of oxygen are in an 85.00-g sample of the substance?

 

a.

64.00 g

 

b.

130.1 g

 

c.

16.00 g

 

d.

55.51 g

 

e.

none of these

 

ANSWER:  

d

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.4

KEYWORDS:  

determining chemical formulas | general chemistry | mass percentage | stoichiometry

 

35. What is the percent by mass of hydrogen in ammonium acetate?

 

a.

7.07%

 

b.

5.23%

 

c.

14.3%

 

d.

3.92%

 

e.

9.15%

 

ANSWER:  

e

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.4

KEYWORDS:  

general chemistry | mass and moles of substance | mass percentage | stoichiometry

 

36. A hydrate of copper(II) sulfate is 25.5% copper by mass.  How many water molecules are there for each unit of copper(II) sulfate?

 

a.

1

 

b.

2

 

c.

3

 

d.

4

 

e.

5

 

ANSWER:  

e

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.4

KEYWORDS:  

determining chemical formulas | empirical formula | general chemistry | stoichiometry

 

37. Which of the following compounds has the same percent composition by mass as styrene, C8H8?

 

a.

cyclobutadiene, C4H4

 

b.

α-ethyl naphthalene, C12H12

 

c.

acetylene, C2H2

 

d.

benzene, C6H6

 

e.

all of these

 

ANSWER:  

e

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.4

KEYWORDS:  

determining chemical formulas | general chemistry | mass percentage | stoichiometry

 

38. Find the percent sulfur (atoms) by mass in sodium sulfide.

 

a.

52.1%

 

b.

58.2%

 

c.

41.1%

 

d.

74.4%

 

e.

73.6%

 

ANSWER:  

c

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.4

KEYWORDS:  

determining chemical formulas | general chemistry | mass percentage | stoichiometry

 

39. You find a compound composed only of element X and hydrogen, and you know that it is 91.33% element X by mass.  Each molecule has 2.67 times as many H atoms as X atoms.  What is element X?

 

a.

Cu

 

b.

Si

 

c.

Cl

 

d.

C

 

e.

Ne

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

difficult

TOPICS:  

3.4

KEYWORDS:  

general chemistry | mass and moles of substance | mole | mole calculations | stoichiometry

 

40. A mixture of NaCl and NaNO3 is 31.7% sodium by mass.  What is the approximate percent of NaCl in this mixture?

 

a.

32%

 

b.

30%

 

c.

38%

 

d.

36%

 

e.

34%

 

ANSWER:  

c

POINTS:  

1

DIFFICULTY:  

difficult

TOPICS:  

3.4

KEYWORDS:  

general chemistry | mass and moles of substance | mass percentage | stoichiometry

 

41. TNT consists of carbon, nitrogen, oxygen, and hydrogen.  It is 37.02% carbon by mass, 18.49% nitrogen by mass, and 42.27% oxygen by mass.  The molar mass of TNT is between 210 g/mol and 245 g/mol.  What is the molecular formula for TNT?

 

a.

C4H7N6O6

 

b.

C6H4N3O6

 

c.

C7H5N3O6

 

d.

C8H12N3O4

 

e.

none of these

 

ANSWER:  

c

POINTS:  

1

DIFFICULTY:  

difficult

TOPICS:  

3.4
3.5

KEYWORDS:  

determining chemical formulas | general chemistry | molecular formula | stoichiometry

 

42. Caffeine consists of carbon, hydrogen, oxygen, and nitrogen.  When 0.1920 g of caffeine is burned in an excess of oxygen, 0.3482 g of carbon dioxide and 0.0891 g water are formed.  Caffeine is 28.84% nitrogen by mass.  Its molar mass is between 190 and 200 g/mol.  What is the formula for caffeine?

 

a.

C6H4N4O4

 

b.

C8H10N4O2

 

c.

C4H5N2O

 

d.

C3H2N2O2

 

e.

none of these

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

difficult

TOPICS:  

3.4
3.5

KEYWORDS:  

determining chemical formulas | general chemistry | molecular formula | stoichiometry

 

43. The empirical formula of a group of compounds is CHCl. Lindane, a powerful insecticide, is a member of this group. The molar mass of lindane is 290.8. How many atoms of carbon does a molecule of lindane contain?

 

a.

6

 

b.

4

 

c.

3

 

d.

8

 

e.

2

 

ANSWER:  

a

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.5

KEYWORDS:  

determining chemical formulas | general chemistry | molecular formula | stoichiometry

 

44. The empirical formula of styrene is CH; its molar mass is 104.1. What is the molecular formula of styrene?

 

a.

C2H4

 

b.

C8H8

 

c.

C6H6

 

d.

C10H12

 

e.

none of these

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.5

KEYWORDS:  

determining chemical formulas | general chemistry | molecular formula | stoichiometry

 

45. What is the empirical formula of a hydrocarbon (a compound that consists of only carbon and hydrogen) that contains 81.7% carbon by mass?

 

a.

C5H12

 

b.

C3H8

 

c.

C4H10

 

d.

C2H6

 

e.

none of these

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.5

KEYWORDS:  

determining chemical formulas | empirical formula | general chemistry | stoichiometry

 

46. The mass percent of iron in an iron oxide is 77.7%.  Find the empirical formula.

 

a.

Fe3O2

 

b.

Fe3O4

 

c.

Fe2O3

 

d.

FeO

 

e.

none of these

 

ANSWER:  

d

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.5

KEYWORDS:  

determining chemical formulas | empirical formula | general chemistry | stoichiometry

 

47. Adipic acid contains 49.32% C, 43.84% O, and 6.85% H by mass. What is the empirical formula?

 

a.

C2H5O4

 

b.

C3H5O2

 

c.

C2HO3

 

d.

C3H3O4

 

e.

C3HO3

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.5

KEYWORDS:  

determining chemical formulas | empirical formula | general chemistry | stoichiometry

 

48. Vitamin C contains the elements C, H, and O. It is known to contain 40.9% C and 4.58% H by mass. The molar mass of vitamin C has been found to be about 180. The molecular formula for vitamin C is

 

a.

C6H8O6

 

b.

C4H6O4

 

c.

C3H4O3

 

d.

C2H3O2

 

e.

none of these

 

ANSWER:  

a

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.5

KEYWORDS:  

determining chemical formulas | general chemistry | molecular formula | stoichiometry

 

49. A 2.00-g sample of an oxide of bromine is converted to 2.936 g of AgBr.  Calculate the empirical formula of the oxide. (molar mass for AgBr = 187.78)

 

a.

BrO3

 

b.

BrO

 

c.

BrO2

 

d.

Br2O

 

e.

none of these

 

ANSWER:  

a

POINTS:  

1

DIFFICULTY:  

difficult

TOPICS:  

3.5

KEYWORDS:  

determining chemical formulas | empirical formula | general chemistry | stoichiometry

 

50. A 0.4647-g sample of a compound known to contain only carbon, hydrogen, and oxygen was burned in oxygen to yield 0.8635 g of CO2 and 0.1767 g of H2O. What is the empirical formula of the compound?

 

a.

C3H3O2

 

b.

C2H2O

 

c.

C6H3O2

 

d.

C3H6O2

 

e.

CHO

 

ANSWER:  

a

POINTS:  

1

DIFFICULTY:  

difficult

TOPICS:  

3.5

KEYWORDS:  

determining chemical formulas | empirical formula | general chemistry | stoichiometry

 

51. When the equation C6H14 + O2 → CO2 + H2O is balanced with the smallest set of integers, the sum of the coefficients is

 

a.

28

 

b.

33

 

c.

47

 

d.

4

 

e.

40

 

ANSWER:  

c

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.6
3.7

KEYWORDS:  

balancing chemical equation | chemical equation | early atomic theory | general chemistry

 

52. Consider the following unbalanced equation:

C4H10 + O2 → CO2 + H2O

For every 1.0 mol of C4H10, ___ mol of O2 is required.

 

a.

1.0

 

b.

8.0

 

c.

13.0

 

d.

6.5

 

e.

none of these

 

ANSWER:  

d

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.7

KEYWORDS:  

balancing chemical equation | chemical equation | early atomic theory | general chemistry

 

53. wPCl5  +  xH2O  → yPOCl3  + zHCl

 

When the equation is properly balanced, what are the coefficients?

 

a.

w = 1, x = 1, y = 1, z = 2

 

b.

w = 2, x = 2, y = 2, z = 2

 

c.

w = 1, x = 2, y = 2, z = 4

 

d.

w = 2, x = 2, y = 2, z = 4

 

e.

none of these

 

ANSWER:  

a

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.7

KEYWORDS:  

balancing chemical equation | chemical equation | early atomic theory | general chemistry

 

54. What is the subscript of aluminum in the formula of aluminum phosphate?

 

a.

3

 

b.

1

 

c.

2

 

d.

0

 

e.

4

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.7

KEYWORDS:  

chemical formula | chemical substance | early atomic theory | general chemistry | ionic substance

 

55. Give (in order) the correct coefficients to balance the following reaction:

H2SnCl6 + H2S → SnS2 + HCl

 

a.

1, 2, 2, 2

 

b.

1, 2, 1, 6

 

c.

1, 1, 1, 6

 

d.

6, 2, 1, 1

 

e.

2, 4, 2, 6

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.7

KEYWORDS:  

balancing chemical equation | chemical equation | early atomic theory | general chemistry

 

56. In the balanced equation for the reaction

[A]P4O6(s) + [B]H2O(l) → [C]H3PO3(aq)

if [A] equals 2, the coefficient [C] equals

 

a.

6

 

b.

4

 

c.

2

 

d.

10

 

e.

none of these

 

ANSWER:  

e

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.7

KEYWORDS:  

balancing chemical equation | chemical equation | general chemistry | stoichiometry

 

57. Which of the following equations correctly describes the combustion of CH4 and O2 to produce water (H2O) and carbon dioxide (CO2)?

 

a.

CH4 + (1/2)O2 → CO2 + H2O

 

b.

CH4 + 2O2 → CO2 + 2H2O

 

c.

CH4 + 3O2 → 2CO2 + H2O

 

d.

CH4 + O2 → CO2 + 2H2O

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.7

KEYWORDS:  

chemical equation | early atomic theory | general chemistry | writing equation

 

58. When the following equation is balanced, what is the sum of the coefficients?

Al2(SO4)3 + Ca(OH)2 → Al(OH)3 + CaSO4

 

a.

10

 

b.

8

 

c.

4

 

d.

9

 

e.

3

 

ANSWER:  

d

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.7

KEYWORDS:  

balancing chemical equation | chemical equation | early atomic theory | general chemistry

 

59. When the equation FeCr2O4 + K2CO3 + O2 → K2CrO4 + Fe2O3 + CO2 is balanced with the smallest set of integers, the sum of the coefficients is

 

a.

9

 

b.

15

 

c.

6

 

d.

37

 

e.

24

 

ANSWER:  

d

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.7

KEYWORDS:  

balancing chemical equation | chemical equation | early atomic theory | general chemistry

 

60. Potassium forms an oxide containing 1 oxygen atom for every 2 atoms of potassium. What is the coefficient of oxygen in the balanced equation for the reaction of potassium with oxygen to form this oxide?

 

a.

0

 

b.

1

 

c.

2

 

d.

3

 

e.

4

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.7

KEYWORDS:  

balancing chemical equation | chemical equation | early atomic theory | general chemistry

 

61. How many moles of sodium phosphate are required to react completely with 3.0 mol of calcium nitrate to form sodium nitrate and calcium phosphate?

 

a.

2.0 mol

 

b.

3.0 mol

 

c.

1.0 mol

 

d.

1.5 mol

 

e.

4.5 mol

 

ANSWER:  

a

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.7

KEYWORDS:  

general chemistry | molar interpretation | stoichiometry | stoichiometry calculation

 

62. When the equation NH3 + O2 → NO + H2O is balanced with the smallest set of integers, the sum of the coefficients is

 

a.

4

 

b.

24

 

c.

12

 

d.

14

 

e.

19

 

ANSWER:  

e

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.7

KEYWORDS:  

general chemistry | molar interpretation | stoichiometry | stoichiometry calculation

 

63. Indium reacts with chlorine to form InCl3. In the balanced equation for this reaction, the coefficient of the indium trichloride is

 

a.

6

 

b.

4

 

c.

2

 

d.

3

 

e.

1

 

ANSWER:  

c

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.7

KEYWORDS:  

balancing chemical equation | chemical equation | early atomic theory | general chemistry

 

64. Consider the following unbalanced equation:

KO2 + H2O → KOH + O2 + H2O2

For every 3.0 mol of KO2, ___ mol of H2O is needed for a complete reaction.

 

a.

6.0

 

b.

2.0

 

c.

3.0

 

d.

1.0

 

e.

none of these

 

ANSWER:  

c

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.7

KEYWORDS:  

general chemistry | molar interpretation | stoichiometry | stoichiometry calculation

 

65. Baking powder, a mixture of cream of tartar (KHC4H4O6, molar mass 188 g/mol) and baking soda (NaHCO3, molar mass 84.0 g/mol), undergoes the following reaction at baking temperatures:

KHC4H4O6 + NaHCO3  →  KNaC4H4O6 + H2O + CO2

(The CO2 makes the cake rise.)  A recipe calls for two level teaspoons (a total of 8.0 g) of cream of tartar.  How much baking soda must be added for both materials to react completely?

 

a.

8.0 g

 

b.

0.45 g

 

c.

3.6 g

 

d.

18 g

 

e.

none of these

 

ANSWER:  

c

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.7

KEYWORDS:  

amounts of substances | general chemistry | stoichiometry | stoichiometry calculation

 

66. A reaction occurs between sodium carbonate and hydrochloric acid producing sodium chloride, carbon dioxide, and water. The correct set of coefficients, respectively, for the balanced reaction is

 

a.

5, 10, 10, 5, 5.

 

b.

1, 2, 2, 1, 1.

 

c.

8, 6, 5, 10, 5.

 

d.

3, 6, 6, 3, 4.

 

e.

none of these

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

difficult

TOPICS:  

3.7

KEYWORDS:  

balancing chemical equation | chemical equation | early atomic theory | general chemistry

 

67. A 6.32-g sample of potassium chlorate was decomposed according to the following equation:

2KClO3 → 2KCl + 3O2

How many moles of oxygen are formed?

 

a.

0.051 mol

 

b.

0.0774 mol

 

c.

0.0344 mol

 

d.

1.65 mol

 

e.

none of these

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.8

KEYWORDS:  

amounts of substances | general chemistry | stoichiometry | stoichiometry calculation

 

68. Sulfuric acid may be produced by the following process:

 

4FeS2 + 11O2 → 2Fe2O3 + 8SO2
2SO2 + O2 → 2SO3
SO3 + H2O → H2SO4

    

How many moles of H2SO4 will be produced form 5.00 mol of FeS2?

 

a.

12.2 mol

 

b.

20.0 mol

 

c.

6.11 mol

 

d.

10.0 mol

 

e.

5.00 mol

 

ANSWER:  

d

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.8

KEYWORDS:  

general chemistry | molar interpretation | stoichiometry | stoichiometry calculation

 

69. Consider the following reaction:

CH4(g) + 4Cl2(g) → CCl4(g) + 4HCl(g)

What mass of CCl4 is formed by the reaction of 8.00 g of methane with an excess of chlorine?

 

a.

14.2 g

 

b.

7.10 g

 

c.

76.7 g

 

d.

1.42 g

 

e.

none of these

 

ANSWER:  

c

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.8

KEYWORDS:  

amounts of substances | general chemistry | stoichiometry | stoichiometry calculation

 

70. When rubidium metal is exposed to air, one atom of rubidium, Rb, combines with two atoms of oxygen. If 1.75 g of rubidium is exposed to air, what will be the mass of the product in grams?

 

a.

0.655 g

 

b.

1.37 g

 

c.

0.328 g

 

d.

2.41 g

 

e.

2.08 g

 

ANSWER:  

d

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.8

KEYWORDS:  

amounts of substances | general chemistry | stoichiometry | stoichiometry calculation

 

71. Iron is produced from its ore by the following reactions:

2C(s) + O2(g) → 2CO(g)
Fe
2O3(s) + 3CO(g) → 2Fe(s) + 3CO2(g)

How many moles of C(s) are needed to produce 2.4 mol Fe(s)?

 

a.

3.6 mol C

 

b.

2.4 mol C

 

c.

5.0 mol ​C

 

d.

1.6 mol C

 

ANSWER:  

a

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.8

KEYWORDS:  

general chemistry | molar interpretation | stoichiometry | stoichiometry calculation

 

72. Consider the following two reactions.

Mg + 2HCl→ MgCl2 + H2
2H2 + O2→  2H2O

​How much water (in grams) is produced from 10.0 g of Mg?

 

a.

3.71 g

 

b.

18.0 g

 

c.

7.41 g

 

d.

1.85 g

 

e.

none of these

 

ANSWER:  

c

POINTS:  

1

DIFFICULTY:  

difficult

TOPICS:  

3.8

KEYWORDS:  

amounts of substances | general chemistry | stoichiometry | stoichiometry calculation

 

73. The refining of aluminum from bauxite ore (which contains 50.% Al2O3 by mass) proceeds by the overall reaction 2Al2O3 + 3C → 4Al + 3CO2. How much bauxite ore is required to give the 5.0 × 1013 g of aluminum produced each year in the United States? (Assume 100% conversion.)

 

a.

1.9 × 1014 g

 

b.

7.6 × 1014 g

 

c.

1.3 × 1013 g

 

d.

5.3 × 1013 g

 

ANSWER:  

a

POINTS:  

1

DIFFICULTY:  

difficult

TOPICS:  

3.8

KEYWORDS:  

amounts of substances | general chemistry | stoichiometry | stoichiometry calculation

 

74. One commercial system removes SO2 emissions from smoke at 95.0°C by the following set of balanced reactions:

SO2(g) + Cl2 → SO2Cl2(g)
SO
2Cl2 + 2H2O → H2SO4 + 2HCl
H
2SO4 + Ca(OH)2 → CaSO4(s) + 2H2O

Assuming the process is 95.0% efficient, how many grams of CaSO4 may be produced from 1.00 × 102 g of SO2 (molar masses: SO2, 64.1 g/mol; CaSO4, 136 g/mol)?

 

a.

47.1 g

 

b.

212 g

 

c.

202 g

 

d.

87.2 g

 

e.

44.8 g

 

ANSWER:  

c

POINTS:  

1

DIFFICULTY:  

difficult

TOPICS:  

3.8

KEYWORDS:  

amounts of substances | general chemistry | stoichiometry | stoichiometry calculation

 

75. How many grams of Ca(NO3)2 can be produced by reacting excess HNO3 with 7.40 g of Ca(OH)2?

 

a.

10.2 g

 

b.

16.4 g

 

c.

7.40 g

 

d.

8.22 g

 

e.

32.8 g

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

difficult

TOPICS:  

3.8

KEYWORDS:  

amounts of substances | general chemistry | stoichiometry | stoichiometry calculation

 

76. How many grams of H2O will be formed when 39.0 g H2 is mixed with 49.6 g O2 and allowed to completely react to form water?

 

a.

88.6 g

 

b.

55.8 g

 

c.

27.9 g

 

d.

351 g

 

e.

59.1 g

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.8
3.9

KEYWORDS:  

general chemistry | limiting reactant | stoichiometry | stoichiometry calculation

 

77. The limiting reactant in a reaction

 

a.

is the reactant for which you have the least number of moles.

 

b.

has the lowest coefficient in a balanced equation.

 

c.

has the lowest ratio of coefficient in the balanced equation to moles available.

 

d.

has the lowest ratio of moles available to coefficient in the balanced equation.

 

e.

none of these

 

ANSWER:  

d

POINTS:  

1

DIFFICULTY:  

easy

TOPICS:  

3.9

KEYWORDS:  

general chemistry | limiting reactant | stoichiometry | stoichiometry calculation

 

78. 29.4 g of Al and 25.0g of Br2 react according to the following equation:

2Al + 3Br2  →  2AlBr3

What mass of AlBr3 is formed, assuming 100% yield?

 

a.

62.6 g

 

b.

291 g

 

c.

27.8 g

 

d.

54.4 g

 

e.

41.7 g

 

ANSWER:  

c

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.9

KEYWORDS:  

general chemistry | limiting reactant | stoichiometry | stoichiometry calculation

 

79. In the reaction

2A + 3B  →  C

4.0 mol A react with 4.0 mol B.  Which reactant is limiting?

 

a.

A is limiting because there are 2 mol of it but 4.0 mol are needed.

 

b.

B is limiting because there are 4.0 mol of it but 6.0 mol are needed.

 

c.

A is limiting because 2 is smaller than 3 (the coefficients in the balanced equation).

 

d.

Neither is limiting because equal amounts (4.0 mol) of each reactant are used.

 

e.

B is limiting because 3 is larger than 2 (the coefficients in the balanced equation).

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.9

KEYWORDS:  

general chemistry | limiting reactant | stoichiometry | stoichiometry calculation

 

80. A 7.66-g sample of AgNO3 is reacted with BaCl2 according to the equation

2AgNO3(aq) + BaCl2(aq) → 2AgCl(s) + Ba(NO3)2(aq)

to give 4.34 g of AgCl. What is the percent yield of AgCl?

 

a.

47.8%

 

b.

56.7%

 

c.

67.2%

 

d.

33.6%

 

e.

20.1%

 

ANSWER:  

c

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.9

KEYWORDS:  

amounts of substances | general chemistry | stoichiometry | stoichiometry calculation

 

81. When 10.0 g of hydrogen gas reacts with 10.0 g of oxygen gas to form water, what is the theoretical yield of water?

 

a.

10.6 g

 

b.

20.0 g

 

c.

11.3 g

 

d.

10.0 g

 

e.

89.4 g

 

ANSWER:  

c

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.9

KEYWORDS:  

general chemistry | limiting reactant | stoichiometry | stoichiometry calculation

 

82. Consider the following reaction:

CH4(g) + 4Cl2(g) → CCl4(g) + 4HCl(g)

What mass of CCl4 will be formed if 1.4moles of methane react with 1.4 moles of chlorine?

 

a.

861 g

 

b.

215 g

 

c.

51.0 g

 

d.

53.8 g

 

e.

21.5 g

 

ANSWER:  

d

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.9

KEYWORDS:  

general chemistry | limiting reactant | stoichiometry | stoichiometry calculation

 

83. In the reaction

2A + B  →  3C + D

3.0 mol A and 2.0 mol B react to form 4.0 mol C.  What is the percent yield of this reaction?

 

a.

50%

 

b.

89%

 

c.

100%

 

d.

75%

 

e.

67%

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

moderate

TOPICS:  

3.9

KEYWORDS:  

general chemistry | limiting reactant | stoichiometry | stoichiometry calculation

 

84. SO2 reacts with H2S as follows:

2H2S + SO2 → 3S + 2H2O

When 7.50 g of H2S reacts with 12.75 g of SO2, which statement applies?

 

a.

6.38 g of sulfur is formed.

 

b.

1.13 g of H2S remains.

 

c.

0.0216 mol of H2S remains.

 

d.

10.6 g of sulfur is formed.

 

e.

SO2 is the limiting reagent.

 

ANSWER:  

d

POINTS:  

1

DIFFICULTY:  

difficult

TOPICS:  

3.9

KEYWORDS:  

general chemistry | limiting reactant | stoichiometry | stoichiometry calculation

 

85. A 15-g sample of lithium is reacted with 15 g of fluorine to form lithium fluoride:

2Li + F2 → 2LiF.

After the reaction is complete, what will be present?

 

a.

2.16 mol lithium fluoride and 0.395 mol fluorine

 

b.

0.789 mol lithium fluoride and 1.37 mol lithium

 

c.

0.789 mol lithium fluoride only

 

d.

2.16 mol lithium fluoride only

 

e.

none of these

 

ANSWER:  

b

POINTS:  

1

DIFFICULTY:  

difficult

TOPICS:  

3.9

KEYWORDS:  

general chemistry | limiting reactant | stoichiometry | stoichiometry calculation

 

86. Consider the electrolysis of a brine solution:

2NaCl(aq) + H2O → Cl2(g) + H2(g) + 2NaOH(aq)

A 10.0-g sample of sodium chloride was placed in 10.0 g of water. If 3.85 g of Cl2 was obtained, what was the percent yield of Cl2?

 

a.

95.8%

 

b.

38.5%

 

c.

19.3%

 

d.

63.5%

 

e.

19.6%

 

ANSWER:  

d

POINTS:  

1

DIFFICULTY:  

difficult

TOPICS:  

3.9

KEYWORDS:  

general chemistry | limiting reactant | stoichiometry | stoichiometry calculation

 

87. Consider the following balanced equation:

A(g) + 5B(g) → 3C + 4D

When equal masses of A and B are reacted, which is limiting?

 

a.

If the molar mass of A is less than the molar mass of B, then B must be limiting.

 

b.

If the molar mass of A is greater than the molar mass of B, then B must be limiting.

 

c.

If the molar mass of A is less than the molar mass of B, then A must be limiting.

 

d.

If the molar mass of A is greater than the molar mass of B, then A must be limiting.

 

e.

More information is needed.

 

ANSWER:  

a

POINTS:  

1

DIFFICULTY:  

difficult

TOPICS:  

3.9

KEYWORDS:  

general chemistry | limiting reactant | stoichiometry | stoichiometry calculation

 

88. Consider the following reaction:

4NH3(g) + 7O2(g) → 4NO2(g) + 6H2O(l)

Consider an experiment in which you react ammonia and oxygen.  At the end of the experiment, you find that you produced 27.0 g of water, and 8.52 g of ammonia is left over.  Calculate the initial mass of ammonia.  Assume the reaction went to completion.

 

a.

34.1 g

 

b.

17.0 g

 

c.

25.5 g

 

d.

68.0 g

 

e.

10.8 g

 

ANSWER:  

c

POINTS:  

1

DIFFICULTY:  

difficult

TOPICS:  

3.9

KEYWORDS:  

general chemistry | molar interpretation | stoichiometry | stoichiometry calculation

 

 

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