Chemistry 11th Edition By Raymond Chang – Test Bank
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Sample Questions
Chapter 4: Reactions in Aqueous Solutions
1. Which
of the following compounds is a strong
electrolyte?
2. A) H2O
B) CH3OH C) CH3CH2OH
D) HF E) NaF
Ans: E Category: Easy
Section: 4.1
2. Which
of the following compounds is a weak
electrolyte?
3. A)
HNO3 B) NaNO3
C) HNO2 D) NaNO2
E) NaOH
Ans: C
Category: Easy Section: 4.1
3. Which
of the following compounds is a strong
electrolyte?
4. A) H2O
D) CH3CH2OH
(ethanol)
5. B) N2
E) KOH
6. C) CH3COOH
(acetic acid)
Ans: E
Category: Easy Section: 4.1
4. Which
of the following compounds is a weak
electrolyte?
5. A)
HCl
D) O2
6. B) CH3COOH
(acetic
acid)
E) NaCl
7. C) C6H12O6 (glucose)
Ans: B
Category: Easy Section: 4.1
5. Which
of the following compounds is a weak
electrolyte?
6. A)
HCl B) NH3
C) C6H12O6 (glucose) D) N2
E) KCl
Ans: B
Category: Easy Section: 4.1
6. Which
of the following compounds is a nonelectrolyte?
7. A) NaF
D) NaOH
8. B)
HNO3
E) C6H12O6 (glucose)
9. C) CH3COOH
(acetic acid)
Ans: E
Category: Easy Section: 4.1
7. Which
of the following compounds is a nonelectrolyte?
8. A)
NaOH
D) KF
9. B)
HNO3
E) CH3COOH
(acetic acid)
10. C) C2H6O
(ethanol)
Ans: C
Category: Easy Section: 4.1
8. Identify
the major ionic
species present in an aqueous solution of Na2CO3.
9. A) Na2+, CO32–
D) Na+, C+, O2–
10. B) Na2+, C2 –, O3
E) Na+, CO32–
11. C) Na+, C4+, O32–
Ans: E
Category: Easy Section: 4.1
9. Identify
the major ionic
species present in an aqueous solution of K2SO4.
10. A) K2+, S6+, O48–
D) 2K+, S6+, 4O2–
11. B) K2+, S6+, 4O2–
E) 2K+, SO42–
12. C) 2K+, S6+, O48–
Ans: E
Category: Easy Section: 4.1
10. Identify
the major ionic
species present in an aqueous solution of NH4ClO4.
11. A) NH4+, Cl–, 4O2-
D) NH4+, ClO4–
12. B) N3-, 4H+, Cl–, 4O2-
E) NH4Cl+, O4–
13. C)
4NH+, 4ClO–
Ans: D
Category: Easy Section: 4.1
11. Identify
the major ionic
species present in an aqueous solution of C6H12O6 (glucose).
12. A) 6
C–, 12 H+, 6 O–
D) C6+, 12
H+, 6 O2-
13. B) 6
C+, 12 H+, 6 O2-
E) no ions are present
14. C) 6
CH2+, 6 O2-
Ans: E
Category: Easy Section: 4.1
12. Identify
the major ionic
species present in an aqueous solution of FeCl3.
13. A) Fe+, Cl3–
B) Fe3+, Cl33-
C) Fe3+, 3 Cl– D) Fe2+, 3
Cl– E) Fe+, 3
Cl–
Ans: C
Category: Easy Section: 4.1
13. Identify
the major ionic
species present in an aqueous solution of C12H22O11 (sucrose).
14. A) 12
C–, 22 H+, 11 O–
D) C12+, 22
H+, 11 O2-
15. B) 12
C+, 22 H+, 11 O2-
E) no ions are present
16. C) 12
CH2+, 11 O2-
Ans: E
Category: Easy Section: 4.1
14. The distinguishing characteristic
of all electrolyte solutions is that they
15. A)
contain
molecules.
D) always contain acids.
16. B)
conduct
electricity.
E) conduct heat.
17. C)
react with other solutions.
Ans: B
Category: Easy Section: 4.1
15. Based
on the solubility rules, which one of the following compounds should be insoluble in water?
16. A)
NaCl B) MgBr2
C) FeCl2 D) AgBr E) ZnCl2
Ans: D
Category: Easy Section: 4.2
16. Based
on the solubility rules, which of the following compounds should be insoluble in water?
17. A) Na2SO4
B) BaSO4 C) CuSO4
D) MgSO4 E) Rb2SO4
Ans: B
Category: Easy Section: 4.2
17. Based
on the solubility rules, which of the following compounds should be insoluble in water?
18. A)
CaCO3 B) (NH4)2CO3
C) Na2CO3 D) K2CO3
E) KNO3
Ans: A
Category: Easy Section: 4.2
18. Based
on the solubility rules, which of the following should be soluble in water?
19. A) Hg2Cl2
B) Na2S C) Ag2CO3
D) Ag2S E) BaSO4
Ans: B
Category: Easy Section: 4.2
19. Based
on the solubility rules, which of the following should be soluble in water?
20. A)
AgBr B) AgCl C) Ag2CO3
D) AgNO3 E) Ag2S
Ans: D Category: Easy
Section: 4.2
20. Based
on the solubility rules, which of the following should be soluble in water?
21. A)
(NH4)3PO4 B) Ca3(PO4)2
C) AlPO4 D) Ag3PO4
E) Mg3(PO4)2
Ans: A
Category: Easy Section: 4.2
21. Based
on the solubility rules, which of the following should be soluble in water?
22. A)
CaSO4 B) BaSO4
C) PbSO4 D) K2SO4
E) AgCl
Ans: D
Category: Easy Section: 4.2
22. Which
of the following will occur when a solution of Pb(NO3)2(aq)
is mixed with a solution of KI(aq) ?
23. A) A
precipitate of KNO3 will form; Pb2+ and
I– are spectator ions.
24. B) No
precipitate will form.
25. C) A
precipitate of Pb(NO3)2 will form; K+ and
I– are spectator ions.
26. D) A
precipitate of PbI2 will form; K+ and
NO3– are spectator
ions.
27. E) A
precipitate of PbI2 will form; Pb2+ and
I– are spectator ions.
Ans: D
Category: Medium Section: 4.2
23. Which
of the following will occur when solutions of CuSO4(aq)
and BaCl2(aq) are mixed?
24. A) A
precipitate of CuCl2 will form; Ba2+ and
SO42– are spectator
ions.
25. B) A
precipitate of CuSO4 will form; Ba2+ and
Cl– are spectator ions.
26. C) A
precipitate of BaSO4 will form; Cu2+ and
Cl– are spectator ions.
27. D) A
precipitate of BaCl2 will form; Cu2+ and
SO42– are spectator
ions.
28. E) No
precipitate will form.
Ans: C
Category: Medium Section: 4.2
24. Which
of the following will occur when solutions of ZnSO4(aq)
and MgCl2(aq) are mixed?
25. A) A
precipitate of ZnCl2 will form; Mg2+ and
SO42– will be
spectator ions.
26. B) A precipitate
of ZnSO4 will form ; Mg2+ and
Cl– will be spectator ions.
27. C) A
precipitate of MgSO4 will form ; Zn2+ and
Cl– will be spectator ions.
28. D) A
precipitate of MgCl2 will form ; Zn2+ and
SO42– will be
spectator ions.
29. E) No
precipitate will form.
Ans: E
Category: Medium Section: 4.2
25. Identify
the precipitate(s) formed when solutions of Na2SO4(aq),
Ba(NO3)2(aq), and NH4ClO4(aq)
are mixed.
26. A)
Ba(ClO4)2
D) BaSO4
27. B)
BaSO4 and (NH4)2SO4
E) NaClO4
28. C) NH4NO3 and
NaClO4
Ans: D
Category: Medium Section: 4.2
26. Identify
the precipitate(s) formed when solutions of NH4Cl(aq),
AgClO3(aq), and NaCl(aq) are mixed.
27. A)
AgCl
D) NH4ClO3
28. B)
AgCl and NH4ClO3
E) AgNH4
29. C) NH4Cl
and NaClO3
Ans: A
Category: Medium Section: 4.2
27. Identify
the precipitate(s) formed when solutions of Ca(ClO4)2(aq),
K2CO3(aq), and NaNO3(aq) are
mixed.
28. A)
CaCO3
D) CaCO3 and
Na2CO3
29. B) Na2CO3
E) KClO4 and
Ca(NO3)2
30. C)
Ca(NO3)2 and NaClO4
Ans: A Category: Medium
Section: 4.2
28. Identify
the precipitate(s) formed when solutions of Pb(NO3)2(aq),
Mg(ClO4)2(aq), and (NH4)2SO4(aq)
are mixed.
29. A)
PbSO4
D) NH4NO3 and
NH4ClO4
30. B)
MgSO4
E) PbSO4 and
MgSO4
31. C) NH4ClO4
Ans: A
Category: Medium Section: 4.2
29. Identify
the correct net ionic
equation for the reaction that occurs when solutions of Pb(NO3)2 and
NH4Cl are mixed.
30. A)
Pb(NO3)2(aq) + 2NH4Cl(aq) ® NH4NO3(aq)
+ PbCl2(s)
31. B) Pb2+(aq)
+ 2Cl–(aq) ® PbCl2(s)
32. C) Pb2+(aq)
+ 2NO3– (aq) + 2NH(aq) +
2Cl–(aq) ® 2NH(aq) + 2NO3– (aq)
+ PbCl2(s)
33. D) NH4+(aq)+
NO3– (aq) ® 2NH4NO3(s)
34. E) No
reaction occurs when the solutions are mixed.
Ans: B
Category: Medium Section: 4.2
30. Identify
the correct net ionic
equation for the reaction that occurs when solutions of AgNO3 and
NH4Cl are mixed.
31. A)
AgNO3(aq) + NH4Cl(aq) ® AgCl(s) + NH4Cl(aq)
32. B) NH4+(aq)
+ NO3–(aq) ® NH4NO3(s)
33. C)
AgNO3(aq) + NH4Cl(aq) ® AgCl(s) + NH4Cl(s)
34. D) Ag+(aq)
+ Cl–(aq) ® AgCl(s)
35. E)
AgNO3(aq) + NH4+(aq)
® NH4AgNO3(s)
Ans: D
Category: Medium Section: 4.2
31. Identify
the correct net ionic
equation for the reaction that occurs when solutions of Ba(ClO4)2 and
K2SO4 are mixed.
32. A) Ba2+(aq)
+ SO42-(aq) ® BaSO4(s)
33. B) 2K+(aq)
+ 2ClO4–(aq) ® K2(ClO4)2(s)
34. C) K+(aq)
+ ClO4–(aq) ® KClO4(s)
35. D)
Ba(ClO4)2(aq) + K2SO4(aq)
® BaSO4(s) + 2KClO4(s)
36. E) Ba2+(aq)
+ K+(aq) + SO42-(aq)
® KBaSO4(s)
Ans: A Category: Medium
Section: 4.2
32. Identify
the correct net ionic
equation for the reaction that occurs when solutions of Na3PO4 and
Ca(NO3)2 are mixed
33. A) Ca2+ +
PO42-(aq) ® CaPO4(s)
34. B)
3Ca2+(aq) + 2PO43-(aq)
® Ca3(PO4)2(s)
35. C) Na+(aq)
+ NO3– ® NaNO3(s)
36. D) Na+(aq)
+ Ca2+(aq) + PO43-(aq)
® NaCaPO4(s)
37. E) 2
Na3PO4(aq) + 3Ca(NO3)2(aq)
® 6NaNO3(s) + Ca3(PO4)2(s)
Ans: B
Category: Medium Section: 4.2
33. The
common constituent in all acid solutions is
34. A) H2
B) H+ C) OH–
D) H2SO4 E) Cl–
Ans: B
Category: Easy Section: 4.3
34. Which
of the following compounds is a weak
acid?
35. A)
HF B) HCl C)
HBr D) HI E) HClO4
Ans: A
Category: Easy Section: 4.3
35. Which
of the following compounds is a strong
acid?
36. A) HF
B) HI C) HClO2
D) H2SO3 E) HNO2
Ans: B
Category: Easy Section: 4.3
36. Which
of the following compounds is a weak
base?
37. A)
KOH B) Sc(OH)3
C) NH3 D) NH4+
E) CO2
Ans: C
Category: Easy Section: 4.3
37. Which
of the following ions is a weak
acid?
38. A) SO42-
B) H2SO4 C) HSO4–
D) HNO3 E) NO3–
Ans: C
Category: Easy Section: 4.3
38. Identify
the major ions
present in an aqueous LiOH solution.
39. A) Li2+, O–, H–
B) Li+, OH– C) LiO–, H+
D) Li+, O2–, H+ E) Li–, OH+
Ans: B
Category: Easy Section: 4.1
39. Identify
the major ions
present in an aqueous HNO3 solution.
40. A) HN+,
O2– B) OH–, NO3–
C) OH–, NO D) H+, N3–, O2–
E) H+, NO3–
Ans: E
Category: Easy Section: 4.3
40. Identify
the major ionic
species present in an aqueous solution of H2SO4.
41. A) S6+, O36– (plus
H2O as a neutral species)
42. B) H+, OH–, S6+, 3O2–
43. C) 2H+, S6+, 4O2–
44. D) H+, HSO4–
45. E) 2H+, SO42–
Ans: D Category: Medium
Section: 4.3
41. Identify
the correct net ionic
equation for the reaction that occurs when solutions of HNO3 and
KOH are mixed?
42. A)
HNO3(aq) + KOH(aq) ® H2O(l)
+ KNO3(aq)
43. B) K+(aq)
+ NO3–(aq) ® KNO3(aq)
44. C)
HNO3(aq) + KOH(aq) ® H2O(l)
+ KNO3(s)
45. D) H+(aq)
+ OH–(aq) ® H2O(l)
46. E)
HNO3(aq) + OH–(aq) ® H2O(l)
+ NO3–(aq)
Ans: D
Category: Medium Section: 4.3
42. Identify
the correct net ionic
equation for the reaction that occurs when solutions of HClO4 and
Ba(OH)2 are mixed.
43. A) H+(aq)
+ 2OH–(aq) ® H2O(l)
44. B) H+(aq)
+ OH–(aq) ® H2O(l)
45. C)
2HClO4(aq) + Ba(OH)2(s) ®
2H2O(l) + Ba(ClO4)2(aq)
46. D)
2HClO4(aq) + Ba(OH)2(s) ®
2H2O(l) + Ba(ClO4)2(s)
47. E) 2H+(aq)
+ Ba(OH)2(s) ® 2H2O(l) + Ba2+(aq)
Ans: B
Category: Medium Section: 4.2
43. Identify
the correct net ionic
equation for the reaction that occurs when solutions of HF and
KOH are mixed.
44. A) H+(aq)
+ OH–(aq) ® H2O(l)
45. B)
HF(aq) + OH–(aq) ® H2O(l) + F–(aq)
46. C) H+(aq)
+ KOH(aq) ® H2O(l) + K+(aq)
47. D)
HF(aq) + KOH(aq) ® H2O(l) + KF(s)
48. E) HF(aq)
+ KOH(s) ® H2O(l) + KF(aq)
Ans: B
Category: Medium Section: 4.3
44. The
oxidation number of N in NaNO3 is
45. A)
+6 B) +5 C)
+3 D) –3 E) None of the above.
Ans: B
Category: Medium Section: 4.4
45. The
oxidation number of S in K2SO4 is
46. A)
+6 B) +4 C)
+2 D) –1 E) None of the above.
Ans: A
Category: Medium Section: 4.4
46. The
oxidation number of Mn in KMnO4 is
47. A)
+8 B) +7 C)
+5 D) –7 E) –8
Ans: B Category: Medium
Section: 4.4
47. The
oxidation number of Fe in K3Fe(CN)6 is
48. A)
+3 B) +2 C)
+1 D) –3 E) –4
Ans: A
Category: Medium Section: 4.4
48. The
oxidation number of Cr in Cr2O72– is
49. A)
–12 B) –7 C)
–2 D) +6 E) +7
Ans: D
Category: Medium Section: 4.4
49. For
the chlorate ion, ClO3– , what are the
oxidation states of the Cl and O, respectively?
50. A) –
1, – 2 B) +5, – 2 C) +6, –
2 D) +7, – 2 E) +2, – 1
Ans: B
Category: Medium Section: 4.4
50. For
the perchlorate ion ClO4– ,
what are the oxidation states of the Cl and O, respectively?
51. A) –
1, – 2 B) +8, – 2 C) +7, –
2 D) +6, – 2 E) +2, – 1
Ans: C
Category: Medium Section: 4.4
51. The
highest possible oxidation number of nitrogen is
52. A)
+8 B) +5 C)
+3 D) +1 E) –3
Ans: B
Category: Easy Section: 4.4
52. For
which one of the following acids is chlorine in the +5 oxidation state?
53. A)
HCl B) HClO C) HClO2
D) HClO3 E) HClO4
Ans: D
Category: Medium Section: 4.4
53. The
highest possible oxidation number of carbon is
54. A)
+8 B) +6 C)
+4 D) +2 E) –4
Ans: C
Category: Easy Section: 4.4
54. Select
the compound in which sulfur has its highest possible oxidation number.
55. A) H2S
B) SO2 C) SCl2
D) H2SO3 E) Na2SO4
Ans: E
Category: Medium Section: 4.4
55. The
oxidation number of N in N2H4 is
56. A)
+4 B) –4 C)
+2 D) –2 E) 0
Ans: D
Category: Medium Section: 4.4
56. Determine
the correct oxidation numbers for all three elements in Rb2SO3 in
the order that the elements are shown in the formula.
57. A)
–2, +6, –2 B) –1, +4, –3 C) +2,
+4, –2 D) +1, +4, –2 E) +1, +6,
–6
Ans: D Category: Medium
Section: 4.4
57. Determine
the correct oxidation numbers for all three elements in Ca(ClO)2 in
the order that the elements are shown in the formula?
58. A)
+2, +1, –2 B) +2, –2, +1 C) +2,
–3, +2 D) –2, +2, –1 E) –2, +3,
–2
Ans: A
Category: Medium Section: 4.4
58. Using
the redox reaction below determine which element is oxidized and which is
reduced.
4NH3 + 3Ca(ClO)2 ®
2N2 + 6H2O + 3CaCl2
1. A) H
is oxidized and N is
reduced
D) Cl is oxidized and O is reduced
2. B) N
is oxidized and Cl is
reduced
E) Cl is oxidized and N is reduced
3. C) N
is oxidized and O is reduced
Ans: B
Category: Medium Section: 4.4
59. How
many total electrons are transferred in the following reaction?
B2H6(g) + 3O2(g) ® B2O3(s) +
3H2O(l)
1. A)
2 B) 3 C) 4
D) 6 E) 12
Ans: E
Category: Medium
Section: 4.4
60. How
many total electrons are transferred in the following reaction?
4 P(s) + 5O2(g) ® 2P2O5(s)
1. A)
5 B) 10 C) 15
D) 20 E) 25
Ans: D
Category: Medium Section: 4.4
61. How
many total electrons are transferred in the following reaction?
2Na(s) + Cl2(g) ® 2NaCl(s)
1. A)
1 B) 2 C) 3
D) 4 E) 5
Ans: B
Category: Medium Section: 4.4
62. Which
one of the following is a redox reaction?
63. A)
2Al(s) + 3H2SO4(aq) ® Al2(SO4)3(aq)
+ 3H2(g)
64. B)
2KBr(aq) + Pb(NO3)2(aq) ® 2KNO3(aq) + PbBr2(s)
65. C)
CaBr2(aq) + H2SO4(aq)
® CaSO4(s) + 2HBr(g)
66. D) H+(aq)
+ OH– (aq) ® H2O(l)
67. E) CO32– (aq)
+ HSO4–(aq) ® HCO3– (aq)
+ SO42– (aq)
Ans: A
Category: Medium Section: 4.4
63. Which
of the following equations does not represent
an oxidation-reduction reaction?
64. A)
3Al + 6HCl ® 3H2 + AlCl3
65. B) 2H2O ®
2H2 + O2
66. C)
2NaCl + Pb(NO3)2 ® PbCl2 + 3NaNO3
67. D)
2NaI + Br2 ® 2NaBr + I2
68. E)
Cu(NO3)2 + Zn ® Zn(NO3)2 +
Cu
Ans: C
Category: Medium
Section: 4.4
64. In
the following chemical reaction the oxidizing
agent is
5H2O2 + 2MnO4– +
6H+ ® 2Mn2+ + 8H2O +
5O2
1. A) H2O2
B) MnO4–
C) H+ D) Mn2+
E) O2
Ans: B
Category: Medium Section: 4.4
65. In
the following chemical reaction the oxidizing
agent is
5S + 6KNO3 + 2CaCO3 ®
3K2SO4 + 2CaSO4 +
CO2 + 3N2
1. A)
S B) N2
C) KNO3 D) CaSO4
E) CaCO3
Ans: C Category: Medium
Section: 4.4
66. Identify
the oxidizing agent in
the following chemical reaction.
2MnO4– + 5H2SO3 ®
2Mn2+ + 5SO42– +
4H+ + 3H2O
1. A)
MnO4–
B) H2SO3 C) Mn2+
D) SO42–
E) H+
Ans: A
Category: Medium Section: 4.4
67. Identify
the reducing agent in
the following chemical reaction.
5Fe2+(aq) + MnO4–(aq)
+ 8H+(aq) ® 5Fe3+(aq) + Mn2+(aq)
+ 4H2O(l)
1. A) Fe2+
B) MnO4–
C) H+ D) Mn2+
E) Fe3+
Ans: A
Category: Medium Section: 4.4
68. Identify
the reducing agent in
the following chemical reaction.
Cd + NiO2 + 2H2O ®
Cd(OH)2 + Ni(OH)2
1. A)
Cd B) NiO2
C) H2O D) Cd(OH)2
E) Ni(OH)2
Ans: A
Category: Medium Section: 4.4
69. What
element is oxidized in
the following chemical reaction?
3Cu + 8HNO3 ® 3Cu(NO3)2 +
2NO + 4H2O
1. A)
Cu B) H C) N
D) O E) H2O
Ans: A
Category: Medium Section: 4.4
70. What
element is oxidized in
the following chemical reaction?
NiO2 + Cd + 2H2O ®
Ni(OH)2 + Cd(OH)2
1. A)
Ni B) Cd C) O
D) H E) This is not a redox reaction.
Ans: B
Category: Medium Section: 4.4
71. What
element is oxidized in
the following chemical reaction?
H2SO4 + Cd(OH)2 ®
2H2O + CdSO4
1. A)
H B) S C) O
D) Cd E) this is not a redox reaction
Ans: E
Category: Medium Section: 4.4
72. What
element is reduced in
the following chemical reaction?
Cu + 2H2SO4 ®
CuSO4 + SO2 + 2H2O
1. A)
Cu B) H C) S
D) O E) H2O
Ans: C
Category: Medium Section: 4.4
73. Identify
the elements that are oxidized and reduced in the following reaction.
KClO3(aq) + 6HBr(aq) ® KCl(aq) + 3Br2(l) +
3H2O(l)
1. A) Br
is oxidized and Cl is
reduced
D) O is oxidized and Cl is reduced
2. B) Cl
is oxidized and H is reduced
E) Cl is oxidized and Br is reduced
3. C) H
is oxidized and O is reduced
Ans: A
Category: Medium Section: 4.4
74. Predict
the products of the following single replacement reaction.
Fe(s) + CuSO4(aq) ®
1. A)
Cu(s) + FeSO4(aq)
D) FeCuSO4(aq)
2. B)
Fe(s) + Cu(s) + SO4(aq)
E) FeO(s) + CuSO3(aq)
3. C)
CuS(s) + Fe2SO4(aq)
Ans: A
Category: Medium Section: 4.4
75. Predict
the products of the following single replacement reaction.
Zn(s) + CoCl2(aq)
®
1. A) No
reaction
occurs
D) ZnCo(aq) + Cl2(g)
2. B)
Co(s) + ZnCl2(aq)
E) ZnCoCl2(aq)
3. C)
CoCl(aq) + ZnCl(aq)
Ans: B
Category: Medium Section: 4.4
76. Predict
the products of the following single replacement reaction.
Ni(s) + Cu(NO3)2(aq)
®
1. A) No
reaction
occurs
D) Ni(NO3)2(aq)
+ Cu(s)
2. B)
NiNO3(aq) + CuNO3(aq)
E) Ni(NO3)2(aq)
+ Cu2+(aq)
3. C)
NiCu(aq) 2 NO3–(aq)
Ans: D
Category: Medium Section: 4.4
77. Which
of the following is an example of a disproportionation
reaction?
78. A) 2C2H6(g) +
7O2(g) ® 4CO2(g) + 6H2O(l)
79. B)
2KBr(aq) + Cl2(g) ® 2KCl(aq) + Br2(l)
80. C) 2H2O2(aq)
® 2H2O(l) + O2(g)
81. D)
CaBr2(aq) + H2SO4(aq)
® CaSO4(s) + 2HBr(g)
82. E)
2Al(s) + 3H2SO4(aq) ® Al2(SO4)3(aq)
+ 3H2(g)
Ans: C
Category: Medium Section: 4.4
78. Which
of the following is NOT a redox reaction?
79. A)
2NaN3(s) ® 2Na(s) + 3N2(g)
80. B) Fe2O3(s) +
2Al(s) ® 2Fe(s) + Al2O3(s)
81. C)
3NO2(g) + H2O(l) ® 2HNO3(aq)
+ NO(g)
82. D) NH4Cl(aq)
+ AgNO3 ® NH4NO3(aq)
+ AgCl(s)
83. E)
2ZnS(s) + 3O2(g) ® 2ZnO(s) + 2SO2(g)
Ans: D
Category: Medium Section: 4.4
79. Which
of the following is NOT a redox reaction?
80. A)
2KBr(aq) + Cl2(g) ® 2KCl(aq) + Br2(l)
81. B)
2Na(s) + 2H2O(l) ® 2NaOH(aq) + H2(g)
82. C) V2O5(s)
+ 5 Ca(l) ® 2 V(l) + 5 CaO(s)
83. D)
2KNO3(s) ® 2KNO2(s) + O2(g)
84. E)
2LiOH(aq) + H2SO4(aq) ® Li2SO4(aq)
+ 2H2O(l)
Ans: E
Category: Medium Section: 4.4
80. Which
of the following represents a precipitation
reaction?
81. A) 2H2(g) +
O2(g) ® 2H2O(l)
82. B)
CaBr2(aq) + H2SO4(aq)
® CaSO4(s) + 2HBr(g)
83. C)
2KNO3(s) ® 2KNO2(s) + O2(g)
84. D)
2KBr(aq) + Cl2(g) ® 2KCl(aq) + Br2(l)
85. E)
2Al(s) + 3H2SO4(aq) ® Al2(SO4)3(aq)
+ 3H2(g)
Ans: B
Category: Easy Section: 4.2
81. Which
of the following represents an acid-base
neutralization reaction?
82. A)
2Al(s) + 3H2SO4(aq) ® Al2(SO4)3(aq)
+ 3H2(g)
83. B) SO2(g) +
H2O(l) ® H2SO3(g)
84. C)
LiOH(aq) + HNO3(aq) ® LiNO3(aq) + H2O(l)
85. D)
2KBr(aq) + Cl2(g) ® 2KCl(aq) + Br2(l)
86. E)
CaBr2(aq) + H2SO4(aq)
® CaSO4(s) + 2HBr(g)
Ans: C
Category: Easy Section: 4.3
82. Which
of the following represents a hydrogen
displacement reaction?
83. A) 2C2H6(g) +
7O2(g) ® 4CO2(g) + 6H2O(l)
84. B)
2KBr(aq) + Cl2(g) ® 2KCl(aq) + Br2(l)
85. C) N2(g) +
3H2(g) ® 2NH3(g)
86. D)
CaBr2(aq) + H2SO4(aq)
® CaSO4(s) + 2HBr(g)
87. E)
2Al(s) + 3H2SO4(aq) ® Al2(SO4)3(aq)
+ 3H2(g)
Ans: E Category: Medium
Section: 4.4
83. Which
of the following represents a combustion
reaction?
84. A) 2C2H6(g) +
7O2(g) ® 4CO2(g) + 6H2O(l)
85. B)
LiOH(aq) + HNO3(aq) ® LiNO3(aq) + H2O(l)
86. C) N2(g) +
3H2(g) ® 2NH3(g)
87. D)
2Na(s) + 2H2O(l) ® 2NaOH(aq) + H2(g)
88. E)
2Al(s) + 3H2SO4(aq) ® Al2(SO4)3(aq)
+ 3H2(g)
Ans: A
Category: Easy Section: 4.4
84. What
type of reaction is the following?
Ca(OH)2(s) + 2 HNO3(aq)
® Ca(NO3)2(aq) + 2 H2O(l)
1. A)
Combination reaction
D) Disproportionation reaction
2. B)
Acid-base neutralization
reaction
E) Combustion reaction
3. C)
Hydrogen displacement reaction
Ans: B
Category: Medium Section: 4.4
85. What
type of reaction is the following?
C2H4(g) + 3 O2(g)
® 2 CO2(g) + 2 H2O(g)
1. A)
Combination
reaction
D) Disproportionation reaction
2. B)
Acid-base neutralization
reaction
E) Combustion reaction
3. C)
Hydrogen displacement reaction
Ans: E
Category: Medium Section: 4.4
86. The
reaction below can be classified as which type of reaction ?
2 NO2(g) + H2O(l)
® HNO2(aq) + HNO3(aq)
1. A)
Combination reaction
D) Disproportionation reaction
2. B)
Acid-base neutralization
reaction
E) Combustion reaction
3. C)
Hydrogen displacement reaction
Ans: D
Category: Medium Section: 4.4
87. What
mass of C6H12O6 (glucose) is needed to prepare 450. mL of a 0.650 M
solution of glucose in water?
88. A)
293 g B) 293 g C) 0.692
g D) 52.7 g E) 125 g
Ans: D
Category: Medium Section: 4.5
88. What
mass of C12H22O11 (sucrose) is needed to prepare 255 mL of a 0.570 M
solution of sucrose in water?
89. A) 8
g B) 145 g C) 153
g D) 0.145 g E) 447 g
Ans: A
Category: Medium Section: 4.5
89. What
mass of K2CO3 is needed to prepare 200. mL of a solution having a
potassium ion concentration of 0.150 M?
90. A) 15
g B) 10.4 g C) 13.8
g D) 2.07 g E) 1.49 g
Ans: D
Category: Medium Section: 4.5
90. What
mass of Na2SO4 is needed to prepare 350. mL of a solution having a sodium
ion concentration of 0.125 M?
91. A) 11
g B) 24.9 g C) 12.4
g D) 6.21 g E) 8.88 g
Ans: A
Category: Medium Section: 4.5
91. What
mass of Li3PO4 is needed to prepare 500. mL of a solution having a
lithium ion concentration of 0.175 M?
92. A) 75
g B) 10.1 g C) 19.3
g D) 30.4 g E) 3.38 g
Ans: E
Category: Medium Section: 4.5
92. A
50.0 mL sample of 0.436 M NH4NO3 is
diluted with water to a total volume of 250.0 mL. What is the ammonium
nitrate concentration in the resulting solution?
93. A) 8
M B) 0.459 M C) 2.18 × 10–2 M
D) 8.72 × 10–2 M E) 0.109 M
Ans: D
Category: Easy Section: 4.5
93. A
20.00 mL sample of 0.1015 M nitric acid is introduced into a flask, and water
is added until the volume of the solution reaches 250. mL. What is the
concentration of nitric acid in the final solution?
94. A) 27
M
D) 3.25 × 10–2 M
95. B) 12
× 10–3 M
E) 5.08 × 10–4 M
96. C)
406 M
Ans: B
Category: Easy Section: 4.5
94. A
3.682 g sample of KClO3 is dissolved in
enough water to give 375. mL of solution. What is the chlorate ion
concentration in this solution?
95. A) 00
× 10–2 M
D) 1.65 × 10–2 M
96. B) 41
× 10–2 M
E) 8.01 × 10–2 M
97. C)
118 M
Ans: E
Category: Medium Section: 4.5
95. A
4.691 g sample of MgCl2 is dissolved in
enough water to give 750. mL of solution. What is the magnesium ion
concentration in this solution?
96. A) 70
× 10–2 M
D) 4.93 × 10–2 M
97. B) 05
× 10–2 M
E) 0.131 M
98. C) 57
× 10–2 M
Ans: C
Category: Medium Section: 4.5
96. A
0.9182 g sample of CaBr2 is dissolved in
enough water to give 500. mL of solution. What is the calcium ion concentration
in this solution?
97. A) 19
× 10–3 M
D) 4.59 × 10–3 M
98. B) 30
× 10–3 M
E) 1.25 × 10–3 M
99. C) 72
× 10–3 M
Ans: A
Category: Medium Section: 4.5
97. 35.0
mL of 0.255 M nitric acid is added to 45.0 mL of 0.328 M Mg(NO3)2.
What is the concentration of nitrate ion in the final solution?
98. A)
481 M B) 0.296 M C) 0.854
M D) 1.10 M E) 0.0295 M
Ans: A
Category: Difficult Section: 4.5
98. 17.5
mL of a 0.1050 M Na2CO3 solution is added to 46.0 mL of 0.1250 M NaCl. What
is the concentration of sodium ion in the final solution?
99. A)
205 M B) 0.119 M C) 0.539
M D) 0.148 M E) 0.165 M
Ans: D
Category: Difficult Section: 4.5
99. 25.0
mL of a 0.2450 M NH4Cl solution is added to 55.5 mL of 0.1655 M FeCl3.
What is the concentration of chloride ion in the final solution?
100.
A) 607 M B) 0.418 M
C) 1.35 M D) 0.190 M E)
0.276 M
Ans: B
Category: Difficult Section: 4.5
100.
A 350. mL solution of 0.150 M HNO3(aq)
is mixed with a solution of 230. mL of 0.240 M HCl(aq). How many moles of H+(aq)
are present in the final solution?
101.
A) 0525 moles H+
D) 0.0539 moles H+
102.
B) 108 moles H+
E) 0.195 moles H+
103.
C) 186 moles H+
Ans: B
Category: Difficult Section: 4.5
101.
A 430. mL solution of 0.230 M HBr(aq) is mixed with a solution
of 225 mL of 0.350 M HClO4(aq). How many moles
of H+(aq) are present in the final solution?
102.
A) 0989 moles H+
D) 0.178 moles H+
103.
B) 0888 moles H+
E) 0.271 moles H+
104.
C) 290 moles H+
Ans: D
Category: Difficult Section: 4.5
102.
A 110. mL solution of 0.340 M HCl(aq) is mixed with a solution
of 330. mL of 0.150 M HNO3(aq). The solution is
then diluted to a final volume of 1.00 L. How many moles of H+ are
present in the final solution?
103.
A) 0869 moles H+
D) 0.374 moles H+
104.
B) 490 moles H+
E) 0.0435 moles H+
105.
C) 415 moles H+
Ans: A Category: Difficult
Section: 4.5
103.
When 38.0 mL of 0.1250 M H2SO4 is
added to 100. mL of a solution of PbI2, a
precipitate of PbSO4 forms. The PbSO4 is
then filtered from the solution, dried, and weighed. If the recovered
PbSO4 is found to have a mass of 0.0471 g, what was the
concentration of iodide ions in the original solution?
104.
A) 10 × 10–4 M
D) 3.11 × 10–3 M
105.
B) 55 × 10–4 M
E) 1.55 × 10–3 M
106.
C) 20 × 10–3 M
Ans: D
Category: Difficult Section: 4.6
104.
When 50.0 mL of a 0.3000 M AgNO3 solution
is added to 50.0 mL of a solution of MgCl2, an
AgCl precipitate forms immediately. The precipitate is then filtered from
the solution, dried, and weighed. If the recovered AgCl is found to have
a mass of 0.1183 g, what as the concentration of magnesium ions in the
original MgCl2 solution?
105.
A) 300
M
D) 2.06 × 10–5 M
106.
B) 25 × 10–3 M
E) 4.13 × 10–3 M
107.
C) 65 × 10–2 M
Ans: B
Category: Difficult Section: 4.6
105.
When 20.0 mL of a 0.250 M (NH4)2S
solution is added to 150.0 mL of a solution of Cu(NO3)2, a
CuS precipitate forms. The precipitate is then filtered from the solution,
dried, and weighed. If the recovered CuS is found to have a mass of
0.3491 g, what was the concentration of copper ions in the original Cu(NO3)2 solution?
106.
A) 65 × 10–3 M
D) 4.87 × 10–2 M
107.
B) 22 × 10–2 M
E) 2.43 × 10–2 M
108.
C) 33 × 10–2 M
Ans: E
Category: Difficult Section: 4.6
106.
34.62 mL of 0.1510 M NaOH was needed to neutralize 50.0 mL of an
H2SO4 solution. What is the concentration of the original
sulfuric acid solution?
107.
A) 0229 M B) 0.218 M
C) 0.0523 M D) 0.209 M E)
0.105 M
Ans: C
Category: Medium Section: 4.7
107.
What volume (mL) of a 0.3428 M HCl(aq) solution is required to
completely neutralize 23.55 mL of a 0.2350 M Ba(OH)2(aq)
solution?
108.
A) 34 mL B) 11.07 mL
C) 16.14 mL D) 32.29 mL
E) 47.10 mL
Ans: D
Category: Medium Section: 4.7
108.
What volume (mL) of a 0.2450 M KOH(aq) solution is required to
completely neutralize 55.25 mL of a 0.5440 M H3PO4(aq)
solution?
109.
A) 06 mL B) 165.8 mL
C) 90.17 mL D) 22.09 mL
E) 368.0 mL
Ans: E
Category: Medium Section: 4.7
109.
The concentration of oxalate ion (C2O42–) in
a sample can be determined by titration with a solution of permanganate ion
(MnO4–) of known
concentration. The net ionic equation for this reaction is
2MnO4– + 5C2O42– +
16H+ ® 2Mn2+ + 8H2O +
10CO2
A
30.00 mL sample of an oxalate solution is found to react completely with 21.93
mL of a 0.1725 M solution of MnO4–.
What is the oxalate ion concentration in the sample?
1. A)
02914 M B) 0.4312 M C) 0.1821
M D) 0.3152 M E) 0.05044 M
Ans: D
Category: Medium Section: 4.8
110.
One method of determining the concentration of hydrogen peroxide
(H2O2) in a solution is through titration with the iodide ion.
The net ionic equation for this reaction is
H2O2 + 2I– +2H+ ®
I2 + 2H2O
A 50.00 mL sample of a hydrogen peroxide solution is found to
react completely with 37.12 mL of a 0.1500 M KI solution. What is the
concentration of hydrogen peroxide in the sample?
5. A)
568 × 10–2 M
D) 0.4041 M
6. B)
2227
M
E) 0.1114 M
7. C)
1010 M
Ans: A Category: Medium
Section: 4.8
111.
Zinc dissolves in hydrochloric acid to yield hydrogen gas:
Zn(s) + 2HCl(aq) ® ZnCl2(aq)
+ H2(g)
What mass of hydrogen gas is produced when a 7.35 g chunk of
zinc dissolves in 500. mL of 1.200M HCl?
1. A)
605 g B) 0.113 g C) 0.302
g D) 0.453 g E) 0.227 g
Ans: E
Category: Medium Section: 4.8
112.
Zinc dissolves in hydrochloric acid to yield hydrogen gas:
Zn(s) + 2HCl(aq) ® ZnCl2(aq)
+ H2(g)
When a 12.7 g chunk of zinc dissolves in 500. mL of 1.450M HCl,
what is the concentration of hydrogen ions remaining in the final
solution?
1. A)
776 M B) 0.388 M C) 0.674
M D) 1.06 M E) 0 M
Ans: C
Category: Medium Section: 4.8
113.
Lithium metal dissolves in water to yield hydrogen gas and aqueous
lithium hydroxide. What is the final concentration of hydroxide ions when
5.500 g of lithium metal is dropped into 750. mL of water?
114.
A) 06 M B) 0.528 M
C) 2.11 M D) 0.792 M E)
0.943 M
Ans: A
Category: Medium Section: 4.8
114.
When solid iron(II) hydroxide is added to water, the resulting
solution contains 1.4×10–3g of dissolved
iron(II) hydroxide per liter of solution. What is the hydroxide ion
concentration in this solution?
115.
A) 8×10–6 M
D) 3.1×10–5 M
116.
B) 6×10–5 M
E) 4.0×10–3 M
117.
C) 5×10–10 M
Ans: D
Category: Difficult Section: 4.5
115.
A 250. mL sample of 0.0328M HCl is partially neutralized by the
addition of 100. mL of 0.0245M NaOH. Find the concentration of
hydrochloric acid in the resulting solution.
116.
A) 00700 M B) 0.0164 M
C) 0.0383 M D) 0.0230 M
E) 0.0575 M
Ans: B
Category: Difficult Section: 4.7
116.
A 350. mL sample of 0.276M HNO3 is
partially neutralized by 125 mL of 0.0120M Ca(OH)2.
Find the concentration of nitric acid in the resulting solution.
117.
A) 210 M B) 0.00632 M
C) 0.203 M D) 0.0240 M E)
0.197 M
Ans: E
Category: Difficult Section: 4.7
117.
158 mL of a 0.148M NaCl solution is added to 228 mL of a 0.369M
NH4NO3 solution. The concentration of ammonium ions in the
resulting mixture is
118.
A) 157 M B) 0.218 M
C) 0.625 M D) 0.369 M E)
0 M
Ans: B
Category: Medium Section: 4.5
118.
1.40 g of silver nitrate is dissolved in 125 mL of water.
To this solution 5.00 mL of 1.50M hydrochloric acid is added, and a precipitate
forms. Find the concentration of silver ions remaining in solution.
119.
A) 7×10–3 M
D) 0.121M
120.
B) 34×10–2 M
E) 5.9×10–3 M
121.
C) 77×10–2 M
Ans: A
Category: Difficult Section: 4.6
119.
Define the terms solution, solute, and solvent.
Ans: A solution is
a homogeneous mixture of two or more substances.
The substance present in a smaller amount is called the solute, while the
substance present in the larger amount is called the solvent.
Category: Easy
Section: 4.1
120.
Identify the following compound as a strong electrolyte, weak electrolyte,
or nonelectrolyte:
Al(NO3)3
Ans: strong electrolyte
Category: Easy
Section: 4.1
121.
Identify the following compound as a strong electrolyte, weak electrolyte,
or nonelectrolyte:
NH4NO3
Ans: strong electrolyte
Category: Easy
Section: 4.1
122.
Identify the following compound as a strong electrolyte, weak electrolyte,
or nonelectrolyte: H3PO4
Ans: weak electrolyte
Category: Easy
Section: 4.3
123.
Identify the following compound as a strong electrolyte, weak electrolyte,
or nonelectrolyte:
H2CO3
Ans: weak electrolyte
Category: Easy
Section: 4.3
124.
Identify the following compound as a strong electrolyte, weak electrolyte,
or nonelectrolyte:
CH3OH (methanol).
Ans: nonelectrolyte
Category: Easy
Section: 4.1
125.
Identify the following compound as a strong electrolyte, weak electrolyte,
or nonelectrolyte:
CH3COOH.
Ans: weak electrolyte
Category: Easy
Section: 4.1
126.
Identify the following compound as a strong electrolyte, weak electrolyte,
or nonelectrolyte:
NH3.
Ans: weak electrolyte
Category: Medium
Section: 4.1
127.
Identify the following compound as a strong electrolyte, weak electrolyte,
or nonelectrolyte:
NH4Cl.
Ans: strong electrolyte
Category: Easy
Section: 4.1
128.
Identify the precipitate(s) formed when solutions of Na3PO4(aq),
Ca(NO3)2(aq), and NH4ClO3(aq)
are mixed.
Ans: Ca3(PO4)2
Category: Medium
Section: 4.2
129.
Identify the precipitate(s) formed when solutions of Hg2(ClO4)2(aq),
(NH4)2SO4(aq), and Rb2SO4(aq)
are mixed.
Ans: Hg2SO4
Category: Medium
Section: 4.2
130.
Identify the precipitate(s) formed when solutions of NaOH(aq),
Ca(ClO3)2(aq), and Ba(OH)2(aq)
are mixed.
Ans: Ca(OH)2
Category: Medium
Section: 4.2
131.
Give an example of a monoprotic
acid.
Ans: HNO3 (for
example)
Category: Easy
Section: 4.3
132.
Give an example of a diprotic
acid.
Ans: H2CO3 (for
example)
Category: Easy
Section: 4.3
133.
Name and give the formulas for six strong acids.
Ans: hydrochloric acid, HCl; hydrobromic acid, HBr;
hydroiodic acid, HI; nitric acid, HNO3;
sulfuric acid, H2SO4; perchloric acid, HClO4
Category: Easy
Section: 4.3
134.
Give an example of a triprotic
acid.
Ans: H3PO4
Category: Easy
Section: 4.3
135.
Write the net
ionic equation for reaction that occurs when aqueous iron(III)
sulfate is added to aqueous sodium sulfide to produce solid iron(III) sulfide
and aqueous sodium sulfate.
Ans: 2Fe3+(aq)
+ 3S2– (aq) ® Fe2S3(s)
Category: Medium
Section: 4.2
136.
Determine the oxidation number of each of the elements in Cs2Cr2O7?
Ans: the oxidation number of Cs is +1; the oxidation
number of Cr is +6; the oxidation number of O is –2
Category: Easy
Section: 4.4
137.
Identify the element being oxidized in the following reaction.
4Al + 3O2 ® 2Al2O3
Ans: Al
Category: Medium
Section: 4.4
138.
Identify the element being reduced in the following reaction.
4Al + 3O2 ® 2Al2O3
Ans: O
Category: Medium
Section: 4.4
139.
Identify the oxidizing
agent in the following reaction.
4Al + 3O2 ® 2Al2O3
Ans: O2
Category: Medium
Section: 4.4
140.
Identify the reducing
agent in the following reaction.
4Al + 3O2 ® 2Al2O3
Ans: Al
Category: Medium
Section: 4.4
141.
Identify the element being oxidized in the following reaction.
2KBr + F2 ® Br2 +
2KF
Ans: Br
Category: Medium
Section: 4.4
142.
Identify the element being reduced in the following reaction.
2KBr + F2 ® Br2 +
2KF
Ans: F
Category: Medium
Section: 4.4
143.
Identify the oxidizing
agent in the following reaction.
2KBr + F2 ® Br2 +
2KF
Ans: F2
Category: Medium
Section: 4.4
144.
Identify the reducing
agent in the following reaction.
2KBr + F2 ® Br2 +
2KF
Ans: Br– (or
KBr)
Category: Medium
Section: 4.4
145.
Determine the oxidation number of each of the elements in BaNaPO4?
Ans: the oxidation number of Ba +2; the oxidation number
of Na is +1; the oxidation number of P is +5; the oxidation number of O is –2
Category: Easy
Section: 4.4
146.
Determine the oxidation number of each of the elements in
NaAl(OH)4?
Ans: the oxidation number of Na is +1; the oxidation
number of Al is +3; the oxidation number of O is –2, the oxidation number of H
is +1
Category: Easy
Section: 4.4
147.
Thorium metal is prepared by reacting thorium oxide with calcium
as shown below.
ThO2 + 2Ca ® Th + 2CaO
Which substance is reduced in
this process?
Ans: Th4+ is
reduced
Category: Medium
Section: 4.4
148.
Thorium metal is prepared by reacting thorium oxide with calcium
as depicted below.
ThO2 + 2Ca ® Th + 2CaO
What is the reducing
agent in this process?
Ans: Ca
Category: Medium
Section: 4.4
149.
Thorium metal is prepared by reacting thorium oxide with calcium
as shown below.
ThO2 + 2Ca ® Th + 2CaO
Which substance is oxidized in
this process?
Ans: Ca
Category: Medium Section: 4.4
150.
Thorium metal is prepared by reacting thorium oxide with calcium
as shown below.
ThO2 + 2Ca ® Th + 2CaO
What is the oxidizing
agent in this process?
Ans: ThO4
Category: Medium
Section: 4.4
151.
Batteries in our cars generate electricity by the following
chemical reaction.
Pb + PbO2 + 2H2SO4 ®
2PbSO4 + 2H2O
Which substance is reduced in
this process?
Ans: Pb4+
Category: Medium
Section: 4.4
152.
Batteries in our cars generate electricity by the following
chemical reaction.
Pb + PbO2 + 2H2SO4 ®
2PbSO4 + 2H2O
What is the reducing
agent in this process?
Ans: Pb
Category: Medium
Section: 4.4
153.
Batteries in our cars generate electricity by the following
chemical reaction.
Pb + PbO2 + 2H2SO4 ®
2PbSO4 + 2H2O
Which substance is oxidized in
this process?
Ans: Pb
Category: Medium
Section: 4.4
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